Chemistry, 24.05.2021 15:50 adstone814

What is the pOH of a
2.6 x 10-6 M H+ solution?

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Answer from: gustavoroggero39

Approximately 8.41 (assuming that the solution is at $\rm 25^\circ C$ , under which $K_{\rm w} = 10^{-14}$ .)

Explanation:

Let ${\rm [H^{+}]}$ and ${\rm [OH^{-}]}$ denote the concentration of $\rm H^{+}$ and $\rm OH^{-}$ respectively.

Let $K_{\rm w}$ denote the self-ionization constant of water. The exact value of $K_{\rm w}\!$ depends on the temperature of the solution. $K_{\rm w} =10^{-14}$ at $\rm 25^\circ C$ .

The product of ${\rm [H^{+}]}$ and ${\rm [OH^{-}]}$ in a solution (with $\rm M$ , or moles per liter, as the unit) is supposed to be equal to the $K_{\rm w}$ value of that solution at the corresponding temperature. In other words:

${\rm [H^{+}]} \cdot {\rm [OH^{-}]} = K_{\rm w}$ .

Rearrange to obtain an expression for ${[\rm OH^{-}]}$ :

$\begin{aligned}{\rm [OH^{-}]} &= \frac{K_{\rm w}}{[\rm H^{+}]}\end{aligned}$ .

Assume that the solution in this question is at $\rm 25^\circ C$ (for which $K_{\rm w} =10^{-14}$ .) For this solution:

$\begin{aligned}{\rm [OH^{-}]} &= \frac{K_{\rm w}}{[\rm H^{+}]} \\ &= \frac{10^{-14}}{2.6 \times 10^{-6}}\approx 3.85\times 10^{-9}\; \rm M\end{aligned}$ .

Hence, the $\rm pOH$ of this solution would be:

$\begin{aligned}\rm pOH &= -\log_{10}{\rm [OH^{-}]} \\&\approx -\log_{10} (3.85 \times 10^{-9}) \approx 8.41 \end{aligned}$ .

Answer from: Quest

here we have to get the change of moles on decrease the volume of the reaction in gas phase.

the per the given options it will decrease by (d) 11-50%

we know, on decreasing the volume of the gas phase reaction the reaction moves to the product side.

the reaction: so₂cl₂ (g) = so₂ (g) + cl₂ (g) total

the moles at equilibrium: 1 - α α α = 1+α

concentrations: 1 - α α α = 1 + α

(concentration = moles/volume, as volume is 1 l)

(where α is the degree of dissociation)

now the dissociation constant in terms of concentration is :

$k_{c}$ = $\frac{[so2cl2] x [cl2]}{[so2cl2]}$

or, $\frac{\alpha ^{2} }{(1-\alpha)v }$

or, $k_{c}$ = $\frac{\alpha ^{2} }{(1-\alpha) }$ (at v = 1l)

the reaction: so₂cl₂ (g) = so₂ (g) + cl₂ (g) total

the moles at equilibrium: 1 - α α α = 1+α

concentrations: (1 - α)/0.5 α/0.5 α/0.5 = (1 + α)/0.5

thus, the dissociation constant in terms of concentration is :

$\frac{[so2cl2] x [cl2]}{[so2cl2]}$

or, $\frac{\alpha ^{2} }{(1-\alpha)0.5 }$

$\frac{\alpha ^{2} }{(1-\alpha) }$ = $\frac{\alpha ^{2} }{(1-\alpha) 0.5}$

so, the change of 1 : 1/0.5

or, 1: 2

thus it will decrease by 50%.

or, as per the given options it will decrease by 11-50%

Answer from: Quest

b. acid is the correct answer @jayxboof all social media

acid : acids are those which accepts an electron-pairs.

base : bases are those which donates ab electron-pairs.

alkali : it is a base that dissolves in water. it is basically a base and the ph greater than 7.

hydroxide ion : it is a poly-atomic ion which is negatively charged.

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