Four samples of the same unknown gas G are listed in the table below. Rank these samples in increasing order of ideality. That is, select 1 next to the sample of G that will behave least like an ideal gas, and select 4 next to the sample of G that will behave most like an ideal gas.

1. third choice

2. last choice

3.second choice

4. first choice

a). in this case, dh> 0 and sd> 0. if t becomes larger, the term "-tds" will become more negative. at some point, it is possible that -dts will be more negative than the dh is positive, and the reaction will become spontaneous. this is probably the correct answer, but you should look at all of the other possibilities and make sure of that.