URGENT IMMEDIATE HELP NEEDED

How many mmols of tris-hcl are there in 100 ml of a 100 mm tris-hcl buffer solution at ph 8.1? note that the 100 mm refers to the sum of tris and tris-hcl concentrations?

28. which is not a reason that water is used to store spent fuel rods from nuclear power plants? water increases the speed of the chain reaction in the fuel rods. water protects nuclear power plant workers from the high temperature and radiation of the fuel rods. water acts as a radiation shield to reduce the radiation levels. water cools the spent rods. salts action

2-bromo-2-methylbutane undergoes an e1 elimination reaction in the presence of ethanol. in the next reaction only one of the possible products is represented. although the product shown is not the major product of the reaction, notice that there is more than one way it can be produced. complete the mechanism and draw the missing substances.