What is responsible for creating the exerted by a gas

The answer for #3 is c but i don't know why

For the following dehydrohalogenation (e2) reaction, draw the zaitsev product(s) resulting from elimination involving c3–c4 (i.e., the carbon atoms depicted with stereobonds). show the product stereochemistry clearly. if there is more than one organic product, both products may be drawn in the same box. ignore elimination involving c3 or c4 and any carbon atom other than c4 or c3.

How many mmols of tris-hcl are there in 100 ml of a 100 mm tris-hcl buffer solution at ph 8.1? note that the 100 mm refers to the sum of tris and tris-hcl concentrations?