How many ways can you choose ten tadpoles from a pool of 20

How much would the freezing point of water decrease if 4 mol of sugar were added to 1 kg of water(k=1.86 c/mol/kg for water and i=1 for sugar

Ineed to find the answer of this question because i dont understand it

Asample of hydrated tin (ii) chloride (sncl2) has a mass of 4.90 g. when it is dehydrated, it has a mass of 4.10 g. which is the correct chemical formula for the hydrate? sncl2•2h2o          sncl2•4h2o          sncl2•6h2o