The external and internal defensive

May someone me with these science questions

Which statement about hf is true? it is zero for any compound in its standard state. it is positive when the bonds of the product store more energy than those of the reactants. it is negative when a compound forms from elements in their standard states. it is zero for any element that is in the liquid state.

What is the pressure of 0.500 moles of carbon dioxide gas in a 2.5 l tank and at a temperature of 301 k? (r=0.0821 l·atm/mol·k) 3.08 atm 1.2 atm 0.23 atm 4.01 atm 4.94 atm