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What is the empirical formula of vanadium 1 oxide given that 20.38 grams of vandium combines with oxygen to form 23.58 grams of the oxide

There are 6.022 x 10^23 atoms of hg in 1 mole of hg. the number of atoms in 4.5 moles of hg can be found by multiplying 4.5 by 6.022 x 10^23 a. 2.7 x 10^24 b. 27 x 10^23 c. 2.71 x10^24 d. 27.099 x 10^23

Calculate the expected ph values of the buffer systems from the experiments (a,b,c,d), using the henderson- hasselbalch equation, ph-pka+log[a-]/[ha]. use for pka values carbonic acid= 6.37, and acetic acid= 4.75.