Please help with this chem question I’ll mark you brainiest it’s due in 15 minutes

Problem #3 (ch. 1, problem 15)the ideal gas law provides one way to estimate the pressure exerted by a gas on a container. the law isí‘ťí‘ť=푛푛푛푛푛푛푉푉more accurate estimates can be made with the van der waals equationí‘ťí‘ť=푛푛푛푛푛푛푉푉â’푛푛푟푟â’푞푞푛푛2푉푉2where the term nb is a correction for the volume of the molecules and the term an2/v2is a correction for molecular attractions. the values of a and b depend on the type of gas. the gas constant is r, the absolutetemperature is t, the gas volume is v, and the number of moles of gas molecules is indicated by n. if n = 1 mol of an ideal gas were confined to a volume of v = 22.41 l at a temperature of 0â°c (273.2k), it would exert a pressure of 1 atm. in these units, r = 0.0826.for chlorine gas (cl2), a = 6.49 and b = 0.0562. compare the pressure estimates given by the ideal gas law and the van der waals equation for 1 mol of cl2 in 22.41 l at 273.2 k. what is the main cause of the difference in the two pressure estimates, the molecular volume or the molecular attractions?

3. how much energy in joules is required to evaporate .0005 kg of liquid ammonia to vapor at the same temperature? 4. how much energy ( in megajoules ) is given up by .75 kg of water at 0c when it freezes to form ice at 0c? 5. explain how heat works between and at critical temperatures?

Assuming complete dissociation of the solute, how many grams of kno3 must be added to 275 ml of water to produce a solution that freezes at -14.5 c? the freezing point for pure water is 0.0 c and k_f is equal to 1.86 c/m