Can someone help its confusing

Which of these would be caused by a chemical change? a) the formation of lava. b) sedimantary rock layering over time. c) metamorphic rock forming from igneous. d) metamorphic rock eroding to form sedimentary rock.

Fill in the coefficients that will balance the following reaction: a0cr2(so4)3 + a1agno3 -> a2cr(no3)3 + a3ag2so4

24. a sports ball is inflated to an internal pressure of 1.85 atm at room temperature (25 °c). if the ball is then played with outside where the temperature is 7.5 °c, what will be the new pressure of the ball? assume the ball does not change in volume nor does any air leak from the ball a) 0.555 atm b) 1.74 atm c) 1.85 atm d) 1.97 atm