A researcher studying the nutritional value of a new candy places a 3.60 g sample of the candy inside a bomb calorimeter and combusts it in excess oxygen. The observed temperature increase is 2.02 °C. If the heat capacity of the calorimeter is
31.10 kJ. K-, how many nutritional Calories are there per gram of the candy?

)benzene and toluene form nearly ideal solutions. consider an equimolar solution of benzene and toluene. at 20 °c the vapour pressures of pure benzene and toluene are 9.9 kpa and 2.9 kpa, respectively. the solution is boiled by reducing the external pressure below the vapour pressure. calculate (i) the pressure when boiling begins, (ii) the composition of each component in the vapour, and (iii) the vapour pressure when only a few drops of liquid remain. assume that the rate of vaporization is low enough for the temperature to remain constant at 20 °c.