18.) In basic aqueous solution, the iodide ion reacts with the hypochlorite ion via the generally agreed mechanism on the right: a.) Identify all intermediates included in this mechanism.
OCl–(aq) + H2O (l) Ý HOCl (aq) + OH– (aq) fast
I– (aq) + HOCl (aq) ↓ HOI (aq) + Cl– (aq) slow
OH–(aq) + HOI (aq) ↓ H2O (l) + OI–(aq) fast
net rxn: I– (aq) + OCl–(aq) ↓ Cl–(aq) + OI–(aq)
b.) Write the rate law that this mechanism predicts for the overall reaction.

Which is a characteristic of mixtures?

Using a value of ksp = 1.8 x 10-2 for the reaction pbcl2 pb+2(aq) + 2cl -(aq). if the value of ksp was determined to be only 1.2 x 10-2: too much solid has dissolved. additional precipitate is forming. the solution is unsaturated. the ions are now combining to reduce their concentrations.

Part b: study of equilibrium on solubility: mg(oh)2(s) ⇌ mg2+(aq) + 2 oh–(aq) cloudy clear (pink) 7. a. b. 8. a. b. 9. 10. 11. 12. when adding concentrated hydrochloric acid, how did the appearance of the equilibrium mixture change? the change in appearance indicated a shift in the point of equilibrium. in which direction did the equilibrium shift? (l) left (r) right explain your answer to question 7a. you should indicate which ion was added to or removed from the equilibrium mixture. when adding edta, how did the appearance of the equilibrium mixture change? the change in appearance indicated a shift in the point of equilibrium. in which direction did the equilibrium shift? (l) left (r) right explain your answer to question 8a. you should indicate which ion was added to or removed from the equilibrium mixture. upon heating in which direction is the equilibrium shifting? upon cooling in which direction is the equilibrium shifting? is the forward reaction a. endothermic explain your answers to questions 9, 10, and 11. (l) left (r) right (l) left (r) right b. exothermic