Can someone help me with these 2 please

Achemistry student weighs out of phosphoric acid , a triprotic acid, into a volumetric flask and dilutes to the mark with distilled water. he plans to titrate the acid with solution. calculate the volume of solution the student will need to add to reach the final equivalence point. round your answer to significant digits.

Imagine that you own a property that is exactly 2.2 acres large. you want to sell your property, but your realtor tells you that you cannot sell your land by the acre. in order to sell your land you need to determine the area you own in units of square meters? given that there are 1.6 kilometers in 1 mile and 640 acres in 1 square mile, what is the area of land that you own in square meters square meters?

What can be added to the examples section of each circle? endothermic: ice melting into water, and a heat pack becoming warm exothermic: a glow stick glowing, and fireworks exploding endothermic: ice melting into water, and an instant ice pack turning cold exothermic: fireworks exploding, and gasoline burning endothermic: a glow stick glowing, and a heat pack becoming warm exothermic: an instant ice pack turning cold, and ice melting into water endothermic: gasoline burning, and an instant ice pack turning cold exothermic: ice melting into water, and an instant ice pack turning cold