I need help with these 2 please help

One way in which the useful metal copper is produced is by dissolving the mineral azurite, which contains copper(ii) carbonate, in concentrated sulfuric acid. the sulfuric acid reacts with the copper(ii) carbonate to produce a blue solution of copper(ii) sulfate. scrap iron is then added to this solution, and pure copper metal precipitates out because of the following chemical reaction: (s) (aq) (s) (aq) suppose an industrial quality-control chemist analyzes a sample from a copper processing plant in the following way. he adds powdered iron to a copper(ii) sulfate sample from the plant until no more copper will precipitate. he then washes, dries, and weighs the precipitate, and finds that it has a mass of .

What the blanks in these lines are ?

In an exothermic reaction at equilibrium, what is the effect of lowering the temperature? a. the reaction makes more products. b. the reaction makes more reactants. c. the reaction is unchanged.