g b. If an intense laser interacts with an atom, the atom can absorb more than one photon from the laser, leading to ionization. If this process goes through a particular atomic transition it is called Resonantly Enhanced Multiphoton Ionization (REMPI). Given the resonant photon from part a, what would be the kinetic energy, in eV, of an electron that started from the ground state and absorbed 2 photons

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answer : (a) volume of the gas = 8.67 ×   l

                (b) second virial coefficient b = -1.21226 l/mole

solution :   given,     t = 300k

                                p = 20atm

                                z = 0.86

                                n = 8.2 mmoles = 8.2 × moles

                                r =   0.082 l atm/k/mol

        find,     (a) volume of gas   and (b) second virial coefficient b at 300k.

formula used :            

                          and            

(a)            

                    = \times 0.082\times 300}{20}[/tex]

                    = 8.67 ×   l

(b)      

                    = (0.00867-1) × 8.659

                    = - 8.5839 l/mole