Why is solubility critical when fighting a hydrocarbon fire?

Unlike other extinguishing agents - water, dry chemical, CO2, etc., a stable aqueous foam can extinguish a flammable or combustible liquid fire by the combined mechanisms of cooling, separating the flame/ignition source from the product surface, suppressing vapors and smothering. It can also secure for extended periods of time against reflash or reignition. Water, if used on a standard hydrocarbon fuel, is heavier than most of those liquids and if applied directly to the fuel surface, will sink to the bottom having little or no effect on extinguishment or vapor suppression. If the liquid fuel heats above 212ºF, the water may boil below the fuel surface throwing the fuel out of the contained area and spreading the fire. For this reason, foam is the primary fire-extinguishing agent for all potential hazards or areas where flammable liquids are transported, processed, stored or used as an energy source.

this is what I found, hope it helps

considering the question as per the attachment

here we can see that the radon nuclide has 222 as the atomic mass number and 86 as the atomic number.

when it undergoes nuclear fission it gives polonium which has atomic mass number as 218 and atomic number will be 84 along with a helium nucleus which has 4 atomic mass number and 2 as its atomic number.

222 = 218 + 4 (atomic mass number)

86 = ? + 2; therefore ? = 86-2 = 84.

the atomic mass number of polonium will be 84.