Voltaic Cells, Help asap please)

Calculate the expected ph values of the buffer systems from the experiments (a,b,c,d), using the henderson- hasselbalch equation, ph-pka+log[a-]/[ha]. use for pka values carbonic acid= 6.37, and acetic acid= 4.75.

Water (2510 g ) is heated until it just begins to boil. if the water absorbs 5.09×105 j of heat in the process, what was the initial temperature of the water?

1) in saturated limewater, [h+ ]=3.98x10-13 m. a) find [oh]-/ b) what is the ph? / c) is the solution acidic, basic, or neutral? / 2) in butter, [h+ ]=6.0x10-7 m. a) find [oh]-/ b) what is the ph? / c) is the solution acidic, basic, or neutral? / 3) in peaches, [oh]=3.16x10-11 m a) find [h+ ]/ b) what is the ph? / c) is the solution acidic, basic, or neutral? / 4) during the course of the day, human saliva varies between being acidic and basic. if [oh]=3.16x10-8 m, a) find [h+ ]/ b) what is the ph? / c) is the solution acidic, basic, or neutral? /