Plz answer the question

Why is the bond angle in a water molecule less than the bond angle of methane? a. the central oxygen atom in water has two lone pairs of electrons, whereas the central carbon atom in methane has no lone pairs. b. the central hydrogen atom in water has one lone pair of electrons, whereas the central carbon atom in methane has two lone pairs. c. the central oxygen atom in water has four lone pairs of electrons, whereas the central carbon atom in methane has only one lone pair. d. the central oxygen atom exerts more repulsive force on surrounding atoms than the central carbon atom in methane does. reset next

As air becomes more dense, (select all that apply) o. air weighs less o. gas molecules are closer together o. air is colder o. air weighs more o. gas molecules are further apart o. air is hotter

Idont understand it 1.what is the boiling point of a solution of 675 grams of ethylene glycol (c2h6o2) in 2.50 liters of water?