In a polar covalent bond, the more electronegative atom pulls electrons closer and gains a slightly charge, while the less electronegative atom has a slightly charge.

In a polar covalent bond, the more electronegative atom pulls electrons closer and gains a slightly negative charge, while the less electronegative atom has a slightly positive charge.

Explanation:

The covalent bond is the chemical bond between two atoms where electrons are shared. This makes the atoms behave as a unit, which we call a molecule. Atoms interact with each other through the outermost electrons forming bonds.

In other words, the covalent bond is formed by sharing a pair of electrons between the two atoms, one coming from each atom. The shared pair of electrons is common to the two atoms and holds them together. So molecules are formed: small groups of atoms linked together by covalent bonds.

In covalent bonds a dipole forms. The atom with the highest electronegativity attracts electrons towards itself, forming a negative dipole around it since the electrons have a negative charge. In the atom with lower electronegativity, the dipole formed is positively charged, since it partially gives up its electrons.

This is, in a polar covalent bond, the more electronegative atom pulls electrons closer and gains a slightly negative charge, while the less electronegative atom has a slightly positive charge.