You are conducting a calorimetry experiment using a calorimeter with 500mL of water in its outer chamber to determine the enthalpy of reaction of a chemical reaction. The initial temperature of the water is 25°C. After the reaction, the temperature of the water is 62.8°C. Disregarding any heat loss to the walls of the container, calculate the ΔHr0. The specific heat of water is 4.18J/(g•K).

it is called acid bonding

answer : (a) volume of the gas = 8.67 ×   l

                (b) second virial coefficient b = -1.21226 l/mole

solution :   given,     t = 300k

                                p = 20atm

                                z = 0.86

                                n = 8.2 mmoles = 8.2 × moles

                                r =   0.082 l atm/k/mol

        find,     (a) volume of gas   and (b) second virial coefficient b at 300k.

formula used :            

                          and            

(a)            

                    = \times 0.082\times 300}{20}[/tex]

                    = 8.67 ×   l

(b)      

                    = (0.00867-1) × 8.659

                    = - 8.5839 l/mole