Temperature definition

Iknow #2 is d. i just need to know why

Achemistry student needs to standardize a fresh solution of sodium hydroxide. he carefully weighs out of oxalic acid , a diprotic acid that can be purchased inexpensively in high purity, and dissolves it in of distilled water. the student then titrates the oxalic acid solution with his sodium hydroxide solution. when the titration reaches the equivalence point, the student finds he has used of sodium hydroxide solution.calculate the molarity of the student's sodium hydroxide solution. be sure your answer has the correct number of significant digits.

The bond energy for the van der waals bond between two helium atoms is 7.9×10−4ev. assuming that the average kinetic energy of a helium atom is (3/2)kbt, at what temperature is the average kinetic energy equal to the bond energy between two helium atoms