1 Volume of certain amount of a gas at 25°C and 100 cm Hg pressure is 80 mL. The gas is
expanded to 160 mL keeping the temperature
constant. Calculate the pressure of the expanded
Numericals based on Boyle's law

P₂ =  50 mmHg

Explanation:

Given data:

Initial volume of gas = 80 mL

Initial pressure of gas = 100 mmHg

Final volume = 160 mL

Final pressure = ?

Temperature = constant

Solution:

The given problem will be solved through the Boyle's law,

"The volume of given amount of gas is inversely proportional to its pressure by keeping the temperature and number of moles constant"

Mathematical expression:

P₁V₁ = P₂V₂

P₁ = Initial pressure

V₁ = initial volume

P₂ = final pressure

V₂ = final volume  

Now we will put the values in formula,

P₁V₁ = P₂V₂

100 mmHg × 80 mL = P₂ × 160 mL

P₂ = 8000 mmHg. mL/ 160 mL

P₂ =  50 mmHg

the electronic configuration of an atom with eight electrons is 1s²2s²2p⁴. the orbital diagrams are shown in the figure.

as per the hunds rule:

1. electrons tend to avoid being in the same orbital as per as practicable.

2. electrons in different orbitals of the same energy will have their spin parallel.

this can be illustrated from the multiplicity of the orbitals of the atom. as there are four electrons in the p orbital and p orbital has 3 sub-shells. the electrons can be fed in different ways as shown in the figure but the correct orbital diagram will be as per the hunds rule.

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