A quantity of gas occupies a volume of 804 mL at a temperature of 27 °C. At what temperature will the volume of the gas be 402 mL, assuming that there is no change in the pressure?

T₂ = 150 K

Explanation:

Given data:

Initial volume of gas = 804 mL

Initial temperature = 27°C (27+273=300 K)

Final temperature = ?

Final volume = 402 mL

Solution:

The given problem will be solve through the Charles Law.

According to this law, The volume of given amount of a gas is directly proportional to its temperature at constant number of moles and pressure.

Mathematical expression:

V₁/T₁ = V₂/T₂

V₁ = Initial volume

T₁ = Initial temperature

V₂ = Final volume  

T₂ = Final temperature

Now we will put the values in formula.

V₁/T₁ = V₂/T₂

T₂ = V₂T₁/V₁  

T₂ = 402 mL × 300 K / 804 mL

T₂ = 120,600 mL.K / 804 mL

T₂ = 150 K

when 25.0 ml of 0.700 mol/l naoh was mixed in a calorimeter with 25.0 ml of 0.700 mol/l hcl, both initially at 20.0 °c, the temperature increased to 22.1 °c. the heat capacity of the calorimeter is 279 j/°c.

the equation for the reaction is:

naoh + hcl → nacl + h₂o

moles of hcl = 0.0250 l hcl ×

0.700

mol hcl

1 l hcl = 0.0175 mol hcl

volume of solution = (25.0 + 25.0) ml = 50.0 ml

mass of solution = 50.0 ml soln ×

1.00

ml soln

= 50.0 g soln

δt=t2-t1

= (22.1 – 20.0) °c = 2.1 °c

the heats involved are

heat from neutralization + heat to warm solution + heat to warm calorimeter = 0

q1+q2+q3=0

nδh+mcδt+cδt=0

0.0175 mol ×

δh

+ 50.0 g × 4.184 j·g⁻¹°c⁻¹ × 2.1 °c + 279 j°c⁻¹ × 2.1 °c = 0

0.0175 mol ×

δh

+ 439.32 j + 585.9 j = 0

0.0175 mol ×

δh

= -1025.22 j

δh=1025.22j0.0175 mol= -58 600 j/mol = -58.6 kj/mol