Please help with everything. Make sure to explain the mechanisms. THANKS

Iknow #2 is d. i just need to know why

Which of the following contributes to the structural rigidity of cellulose? adjacent glucose polymers are stabilized by hydrogen bonding. glucose residues are joined by (α1→4) linkages. cellulose is a highly branched molecule. the conformation of the glucose polymer is a coiled structure.

Which of the following is an indication that a substance has undergone a chemical change? a. no new product has been formed. b. the color of the substance has not changed. c. the original constitute has not changed. d. the molecular structure has changed.