Please someone help me.
. PLEASE HELP ME, ANYONE, PLEASE JUST THIS QUESTION I AM BEGGING

Initially, the balloon had 3.0 liters of gas at a pressure of 400 kpa and was at a temperature of 294 k. if the balloon is cooled to 277 k and its volume decreased to 1 l, what will the new pressure in the balloon be?

Explain how the integumentary system plays a crucial role in the ability to maintain homeoestasis

A3.37-mg sample of protein was chemically digested to convert its nitrogen into ammonia and then diluted to 100.0 ml. then 10.0 ml of this solution was placed in a 50-ml volumetric flask and treated with 5 ml of phenol solution plus 2 ml of sodium hypochlorite solution. the sample was diluted to 50.0 ml, and the absorbance at 625 nm was measured in a 1.00-cm cuvette and found to be 0.486. for reference, a standard solution was prepared from 10.0 mg of nh4cl (molar mass = 53.49 grams/mole) dissolved in 1.00 l of water. then 10.0 ml of this standard was placed in a 50-ml volumetric flask, treated in the same manner as the unknown, and the absorbance found to be 0.323. finally, a reagent blank was prepared using distilled water in place of unknown, it was treated in the same manner as the unknown, and the absorbance found to be 0.076. calculate the weight percent of nitrogen in the protein.