Can you answer question 9 a and b

You are making a solution of calcium chloride dissolved in water. you add solid, stir, and it dissolves. you add just a spatula tip full, stir, and the solid does not dissolve. how could you describe the solutions before and after adding the spatula tip amount

Given the following at 25c calculate delta hf for hcn (g) at 25c. 2nh3 (g) +3o2 (g) + 2ch4 (g) > 2hcn (g) + 6h2o (g) delta h rxn= -870.8 kj. delta hf=-80.3 kj/mol for nh3 (g), -74.6 kj/mol for ch4, and -241.8 kj/mol for h2o (g)

How is the way a mixture is combined different from how a compound is combined?