How many grams of propanol (C3H7OH, 60.10 g/mol) would be needed to make 750 mL of a solution with an osmotic pressure of 25 atm at 25°C? (R = 0.0821 L. atm/K. mol)

It takes 945.kj/mol to break a nitrogen-nitrogen triple bond. calculate the maximum wavelength of light for which a nitrogen-nitrogen triple bond could be broken by absorbing a single photon.

Can someone me with these questions plz.

24. a sports ball is inflated to an internal pressure of 1.85 atm at room temperature (25 °c). if the ball is then played with outside where the temperature is 7.5 °c, what will be the new pressure of the ball? assume the ball does not change in volume nor does any air leak from the ball a) 0.555 atm b) 1.74 atm c) 1.85 atm d) 1.97 atm