A solution is prepared by dissolving 0.23 mol of butanoic acid and 0.27 mol of sodium butanoate in water sufficient to yield 1.00L of solution. The addition of 0.05 mol of HCl to this buffer solution causes the pH to drop slightly. The pH does not decrease drastically because the HCl reacts with the present in the buffer solution. The Ka of butanoic acid is 1.36 x 10-3.

thats how its supposed to be

answer : one can design an experiment using a liquid and an additive that can be added to the liquid and observe the chemical changes in the reaction species.

one would need a beaker which is filled with a known amount of the liquid in which thermometer is placed to measure the temperature changes; after addition of the additive to the liquid solution one can note down the temperature change and find whether the reaction is endothermic or exothermic in nature. by subtracting the initial temperature value with the final temperature one can find the temperature changes.

various combinations of liquid and additive can be used. liquid in this case can be a known quantity of water and additives can be epsom salt or without epsom salt the experiment can be conducted to notice the changes. water and ice, hydrogen peroxide and dry yeast, vinegar and baking soda,etc.