A solution of methylamine ( CH3NH2 ), a weak base, has an initial concentration of 0.195 M. Methylamine has a Kb of 4.4×10−4. Calculate the pH of the solution.

12

Explanation:

Let's consider the basic reaction of methylamine.

CH₃NH₂ + H₂O ⇄ CH₃NH₃⁺ + OH⁻

The concentration of the weak base is Cb = 0.195 M and the basic dissociation constant is Kb = 4.4 × 10⁻⁴. We can calculate the concentration of OH⁻ using the following expression.

[OH⁻] = √(Kb × Cb)

[OH⁻] = √(4.4 × 10⁻⁴ × 0.195) = 9.3 × 10⁻³ M

The pOH is:

pOH = -log [OH⁻] = -log 9.3 × 10⁻³ = 2.0

The pH is:

pH + pOH = 14

pH = 14 - pOH = 14 - 2.0 = 12

"among the transition metal elements, manganese and zinc have a slight lowering of electronegativities. the reason behind this is that the nuclear charges of these elements are slightly weaker than the other transition metal elements due to the way their valence electrons are filled up. both manganese and zinc have their valence electrons filled up to the 4th shell with 1 pair of electrons (4s2) completely occupying it. although the electrons in the 3rd shell (3d) are yet to be paired since the outer most shell is filled up, the ability of the nucleus to attract electrons is lessened. hence,   the electronegativity (or the ability to attract electrons) is lessened."