Hi .
What are the basic topics that govern Chemistry.

Ithink this is what you meant. the temperature at which a liquid begins to boil is called the boiling point. the boiling point of water is 212°f or 100°c.  and at that point will start to turn into steam (gas)

The problem here is that according to aufbau principle before 3d orbital 4s subshell comes.after filling 3p orbital with electrons you have 4 electrons left, you place two in 4s with opposite spin and the other two in 3d in any of its two orbitals of total five orbitals with the same spin.