20. In the previous combustion experiment, the technician determined that the mass of the firewood and oxygen reactants before burning was 2.72 kg, and the mass
of the cooled ash that remained after burning was 0.095 kg.
During that combustion experiment, the temperature inside the burning chamber
was extremely hot, and the temperature on the outside of the chamber was also
extremely hot. The technician was careful not to place his hands on the outside
surface of the chamber during the combustion experiment to avoid getting
burned. Is this burning chamber an example of an open system, a closed system,
or an isolated system? Explain your answer.

answer : the correct answer is 2) hno₃ and naoh .

arrhenius concept of acid and base :

acid :

according to arrhenius acid are those which release h⁺ or hydronium ion (h₃o⁺) in aqueous solution .

example : hcl +h₂o ↔ h₃o⁺ + cl⁻

hcl is giving h₃o⁺ ion in water , hence it is an arrhenius acid .

base :

according to arrhenius , bases are those which releases oh⁻ ions in aqueous solution .

example : koh (aq) ↔ k⁺ + oh⁻

since koh is producing oh⁻ ions hence , it is an arrhenius base .

checking the options :

1) ch₃oh and naoh :

ch₃oh is known as methanol , an organic compound , which is neutral compound . the dissociation of ch₃oh is negligible . it is very very weak acid (ka = 3.2 * 10 ⁻¹² ) .

naoh being ionic gives na⁺ and oh⁻ ions in aqueous solution as :

naoh ↔ na⁺ + oh⁻ . hence it is an arrhenius base

it can be concluded that ch₃oh and naoh is not arrhenius acid and base.

2) hno₃ and naoh :

hno₃ is an ionic compound which gives ions h⁺ and no₃⁻ ion in aqueous solution as:

hno₃ + h₂o ↔ h₃o⁺ + no₃⁻

since it is giving h⁺ ion . hno₃ is arrhenius acid .

naoh being ionic gives na⁺ and oh⁻ ions in aqueous solution as :

naoh ↔ na⁺ + oh⁻

. hence it is an arrhenius base .

it can be said that hno₃ and naoh are arrhenius acid and base.

3) ch₃oh and hcl

as discussed ch₃oh is neutral compound .

while hcl in aqueous solution dissociates to give h⁺ and cl⁻ ions as :

hcl + h₂o→ h₃o⁺ + cl⁻ . so hcl is arrhenius acid .

hence , ch₃oh and hcl are not arrhenius acid and base.

4) hno₃ and hcl :

hno₃ as discussed gives h⁺ in aqueous solution , while hcl also gives h⁺ in aqueous solution .

hence both hno₃ and hcl are arrhenius acid they are not acid and base .

so the arrhenius acid and base are 2) hno₃ and naoh.