Explain why the first ionisation energy of krypton is greater then the first ionisation energy of bromine

Kr has one more electron than br and so, the nuclear charge increase, which means the nuclear attraction between the nucleus and outer most electron will increase and so will be harder to remove the electron from Kr than Br, so Kr has higher 1st ionisation.

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the ideal gas law equation is as follows

pv = nrt

where p - pressure

v - volume

n - number of moles

r - universal gas constant

t - temperature

so if the pressure, volume and temperature are already known

we are left with n and r

since r is the universal gas constant that has a known fixed value then r too is known

so we are left with 'n'

once we know temperature volume and pressure

we can find the number of moles of gas present using the ideal gas law equation

this is not my own answer, this is an answer for the same question by the user blahblahmali. i do not claim ownership of this account.