An amphoteric salt is one that contains an anion that can act as either an acid or a base in water. Baking soda, NaHCO3, is an example. By combining the ionization and hydrolysis reactions of the anion, you get the principle reaction that occurs when this salt is dissolved in water. 2HCO3-(aq) CO32-(aq) + H2CO3(aq)
The pH for such, a solution is given by
pH = pKa1 + pKa2/2
where Ka1 and Ka2 are the ionization constants of the acid (in this case, H2CO3). Note that the pH of the solution is independent of the salt concentration. Calculate the pH of a NaHCO3 solution.

pH = 8.34

Explanation:

The equilbriums of the amphoteric HCO₃⁻ (Ion of NaHCO₃) are:

H₂CO₃ ⇄ HCO₃⁻ + H⁺ Ka1 -Here, HCO₃⁻ is acting as a base-

HCO₃⁻⇄ CO₃²⁻ + H⁺ Ka2 -Here, is acting as an acid-

Where Ka1 = 4.3x10⁻⁷ and Ka2 = 4.8x10⁻¹¹. As pKa = -log Ka:

pKa1 = 6.37; pKa2 = 10.32

As the pH of amphoteric salts is:

pH = (pKa1 + pKa2) / 2

answer: the value of enthalpy change will be -152.80 kj.

solution:

pressure = 1atm , temperature = = 298 k

given that pressure and temperature are same in both gases , the number of moles of both gases can be determined by the ideal gas equation.

according to reaction 3 moles no are reacting with 1 mol of ,then 0.49 mol of no will react with moles of ozone that is 0.16 moles of ozone. since, no is limiting reagent and is an excessive reagent.

enthalpy change for the reaction between the given volumes of the gases is :