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Chemistry, 02.07.2020 17:01 10040813

A very simple assumption for the specific heat of a crystalline solid is that each vibrational mode of the solid acts independently and is fully excited and thus cv=3NAkB=24.9 kJ/(kmolā‹…K). This is called the law of Dulong and Petit. Calculate the Debye specific heat (in units of kJ/(kmolā‹…K) of diamond at room temperature, 298 K. Use a Debye temperature of 2219 K.

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