Next, a chemical reaction of interest was conducted in the same constant volume calorimeter. The neutralization reaction of HCl(aq) with NaOH(aq) caused the temperature of the calorimeter to rise by 2.46 °C. What is the change in internal energy ΔU of the neutralization reaction in kJ?

A constant volume calorimeter (bomb calorimeter) was calibrated by performing in it a reaction in which 5.23 kJ of heat energy was released, causing the calorimeter to rise by 7.33 °C. What is the heat capacity Cy of the calorimeter

Explanation:

the heat capacity of the calorimeter is

Now that our  heat capacity of the calorimeter is 0.714kJ/°C

we can easily calculate  the change in internal energy ΔU of the neutralization reaction

or

Δ T = 2.46 °C

answer: - 3.) the oxidation state of nitrogen in no changes from +2 to 0, and the oxidation state of carbon in co changes from +2 to +4 as the reaction proceeds.

solution: - as per the rules, oxidation number of oxygen in its compounds is -2. the sum of oxidation numbers of all the elements of a molecule or compound is zero.

also, the oxidation number in elemental form is zero.

in no, the oxidation number of o is -2 so the oxidation number of n is +2 so that the sum is zero.

similarly, the oxidation number of c in co is +2 and o is -2.

on product side the oxidation number of n is 0 as it is in the elemental form() .

oxidation number of c in carbon dioxide is +4 as there are two oxygen in it and we know that each oxygen is -2.

so, oxidation number of n is changing from +2 to 0 and the oxidation number of c is changing from +2 to +4.

since nitrogen is reduced and hence no is acting as an oxidizing agent. carbon is oxidized and so co is acting as a reducing agent.

so, the right choice is number 3.)the oxidation state of nitrogen in no changes from +2 to 0, and the oxidation state of carbon in co changes from +2 to +4 as the reaction proceeds.