Please help ASAP I need 1 2 and 3

Two nitro no2 groups are chemically bonded to a patch of surface. they can't move to another location on the surface, but they can rotate (see sketch at right). it turns out that the amount of rotational kinetic energy each no2 group can have is required to be a multiple of ε, where =ε×1.010−24 j. in other words, each no2 group could have ε of rotational kinetic energy, or 2ε, or 3ε, and so forth — but it cannot have just any old amount of rotational kinetic energy. suppose the total rotational kinetic energy in this system is initially known to be 32ε. then, some heat is removed from the system, and the total rotational kinetic energy falls to 18ε. calculate the change in entropy. round your answer to 3 significant digits, and be sure it has the correct unit symbol.

7. using your knowledge of colligative properties explain whether sodium chloride or calcium chloride would be a more effective substance to melt the ice on a slick sidewalk. use 3 – 4 sentences in your explanation. 8. when a 2.5 mol of sugar (c12h22o11) are added to a certain amount of water the boiling point is raised by 1 celsius degree. if 2.5 mol of aluminum nitrate is added to the same amount of water, by how much will the boiling point be changed? show all calculations leading to your answer or use 3 – 4 sentences to explain your answer. 9. if 5.40 kcal of heat is added to 1.00 kg of water at 100⁰c, how much steam at 100⁰c is produced? show all calculations leading to an answer. 10. the freezing of water at 0⁰c can be represented as follows: h2o (l) ↔ h2o(s) the density of liquid water is 1.00 g/cm3. the density of ice is 0.92 g/cm3. in 3 – 4 sentences explain why applying pressure causes ice to melt.

A50.0g sample of liquid water at 0.0 c ends up as ice at -20.0 c. how much energy is involved in this change?