Help Asap, timed assignment here

Which of these would be caused by a chemical change? a) the formation of lava. b) sedimantary rock layering over time. c) metamorphic rock forming from igneous. d) metamorphic rock eroding to form sedimentary rock.

What is the mass of 0.46 mil of mgcl2

3. how much energy in joules is required to evaporate .0005 kg of liquid ammonia to vapor at the same temperature? 4. how much energy ( in megajoules ) is given up by .75 kg of water at 0c when it freezes to form ice at 0c? 5. explain how heat works between and at critical temperatures?