What is the effect of decreasing the volume of the reaction mixture? What is the effect of decreasing the volume of the reaction mixture? Decreasing the volume causes the reaction to shift right. Decreasing the volume causes the reaction to shift left. Decreasing the volume does not cause any shift.

By decreasing the volume, the equilibrium will shift to the side with the smallest amount of particles

Explanation:

Step 1: Data given

The principle of Le Chatelier says:

When the volume is decreased, the equilibrium will shift to the side of the smallest number of particles.

2NOBr(g) ⇌ 2NO(g)+Br2(g)

In the following example, we have 2 moles of NOBr (on the left side) and 3 moles of gas on the right side. This means the left side, the reactant side, has the smallest number of particles.

The equilibrium will here shift to the left side, the side of NOBr.

In the following example

2NO2(g) ⇌ N2O4(g)

We have 2moles of NO2 on the left side and 1 mol of N2O4 on the right side.

By decreasing the volume, the equilibrium will shift to the side of the smallest number of moles. Here this is the right side, the side of N2O4.