Which chemical equation represents the reaction of an Arrhenius acid and an Arrhenius base?

(1) Na2CO3 + CaCl2 —> 2 NaCl + CaCO3

(2) Ni(NO3)2 + H2S —> NiS + 2 HNO3

(3) NaCl + AgNO3 —> AgCl + NaNO3

(4) H2SO4 + Mg(OH)2 —> MgSO4 + 2 H20

Is a logical series of steps

Ithink that the use of creativity in the sciences entails that one produce something out of nothing or from another thing. with this, i think that the he wrote down his results as four parts of the atomic theory is the manifestation of the  creativity of john dalton.

The answer is tea due to the main ingredient being a herb that grows from the ground and sugar that grows from a stalk, i hope this : )     p.s.  can i be brainliest?