Molecules such as ammonia, nitrite, and H2S have more positive reduction potentials than the NAD(P) /NAD(P)H conjugate redox pair. How do chemolithotrophs transfer electrons to the less positive NAD from the more positive inorganic energy sources they utilize as fuels in order to gain reducing power

explanation:

metals have excess of electrons whereas non-metals have deficiency of electrons. thus, in order to gain stability metals easily donate their electrons to the non-metals.

for example, electronic configuration of sodium is and electronic configuration of phosphorous is .

when a phosphorous atom and sodium atom combine together then sodium will donate is extra one electron to the phosphorous atom. as a result there will be formation of ionic bond between sodium and phosphorous.

the reaction will be as follows.

there, are three sodium sodium atoms and each of them will donate its one extra electron to phosphorous atom. thus, the sub-shell of phosphorous gets completely filled.  

thus, we can conclude that electrons are transferred from atoms of sodium to atoms of phosphorous. this transfer makes the sodium atoms donate one electron and the phosphorous atoms to gain one electron. as a result, the sodium and phosphorus atoms strongly attract each other.

atomic mass = 39

number of neutrons = 20

number of protons= 19

electronic configuration = 1s2 2s2 2p6 3s2 3p6 4s1

the number of electron in first shell = 2

number of electrons in n=3 shell = 8