Chemistry, 24.02.2020 16:45 sanfordl

Use the standard reaction enthalpies given below to determine ΔH°rxn for the following reactionP4(g) + 10 Cl2(g) → 4PCl5(s) ΔH°rxn = ?Given:PCl5(s) → PCl3(g) + Cl2(g) ΔH°rxn = +157 kJP4(g) + 6 Cl2(g) → 4 PCl3(g) ΔH°rxn = -1207 kJ

Answers: 1

Show answers

Answers

Answer from: ryliepeloquinf

Therefore $\bigtriangledown H^\circ_{rxn}$ = -1835 KJ

Explanation:

Enthalpy is denoted by H.

Enthalpy: Total heat change in a chemical reaction is called enthalpy.

The change of entalpy of a reaction is denoted by $\bigtriangledown H^\circ_{rxn}$

Hass's Law:The change in enthalpy of any process can be determined by calculating the sum of change in enthalpy of each of the steps involved in the process.

g= gas

S= solid

P₄(g)+10Cl₂(g)→ 4Cl₅(s) $\bigtriangledown H^\circ_{rxn}$ =?

PCl₅(s)→ PCl₃(g)+Cl₂(g) .......(1) $\bigtriangledown H^\circ_{rxn}$ = +157KJ

P₄(g)+6Cl₂(g)→ 4PCl₃(g).............(2) $\bigtriangledown H^\circ_{rxn}$ = -1207 KJ

If we flip a reaction the value of enthalpy will be change positive to negative or nagative to positive but the numerical value will be remain same.

We need rearrange the equation (1) because in the required equation Cl₂ is on the left side. So we flip the first equation.

PCl₃(g)+Cl₂(g)→PCl₅(s)......(3) $\bigtriangledown H^\circ_{rxn}$ = -157KJ

Multiplying 4 with equation (3)

4 PCl₃(g)+4Cl₂(g)→4PCl₅(s)......(4) $\bigtriangledown H^\circ_{rxn}$ =4×( -157)KJ= -628 KJ

Adding equation (2) and (4) we get

P₄(g)+6Cl₂(g)+4 PCl₃(g)+4Cl₂(g)→4PCl₃(g)+4PCl₅(s) $\bigtriangledown H^\circ_{rxn}$ =( -1207-628)KJ

⇒P₄(g)+10Cl₂(g)→4PCl₃(g)-4PCl₃(g)+4PCl₅(s) $\bigtriangledown H^\circ_{rxn}$ = - 1835KJ

⇒P₄(g)+10Cl₂(g)→ 4Cl₅(s) $\bigtriangledown H^\circ_{rxn}$ = -1835 KJ

Therefore $\bigtriangledown H^\circ_{rxn}$ = -1835 KJ

Answer from: Quest

Ithink about 50 % of an original isotope's number of atoms remain

Answer from: Quest

Note that 2 mol dm⁻³ = 2 mol/(dm³)outline: we're given the concentration of hcl, which is 2 mol dm⁻³ (cubic meters in the denominator can represent volume, so i know this is concentration). we're an amount of calcium carbonate caco₃, which is 5 g. we're presented with a chemical equation which includes caco₃ and hcl. we are told to find the volume of hcl. from what we see so far, this seems to be a stoichiometry problem. we'll have to use the given information about calcium carbonate to find the amount of moles of hcl needed to fully react with calcium carbonate. then we'll have information about the moles of hcl and the concentration of hcl; that will be enough to figure out volume according to the formula concentration = moles / volume.======all the answer choices are not in dm.convert the given concentration so that it uses cm⁻³.we can use conversion factors. we have to cube our conversion factors so that dimensional analysis works.we can convert to meters first, using the fact that 10 dm = 1 m ⇔ 10³ dm³ = 1 m³then we use the fact that 10² cm = 1 m ⇔ (10² cm)³ = (1 m)³ ⇔ 10⁶ cm³ = 1 m³so converting: $\dfrac{\text{2 mol}}{\text{dm}^{3}} \cdot \dfrac{\text{10}^3\text{ dm}^3}{\text{1 m}^3} \cdot \dfrac{\text{1 m}^3}{10^6\text{ cm}^3} \\ \\ = \dfrac{\text{2 mol}}{1} \cdot \dfrac{\text{10}^3}{1} \cdot \dfrac{1}{10^6\text{ cm}^3} \qquad \text{\footnotesize cancelling units} \\ \\ = \dfrac{2\text{ mol}}{10^3 \text{ cm}^3} \\ \\ = 0.002\text{ mol/cm}^3$ now we have to find the moles of hydrochloric acid neededfind the moles of calcium carbonate. we have to find the molar mass of calcium carbonate, caco₃, which can be found by molar mass = (mass ca) + (mass c) + 3(mass o) = 40 + 12 + 3(16) = 100 g/molconvert the given 5 g to moles: mol caco₃ = 5 g caco₃ * 1 mol/(100 g) = 0.05 mol caco₃use stoichiometry (ratios) to figure out the moles of hcl needed. ratio wise, there's 2 hcls for every caco₃, so use dimensional analysis mol hcl = mol caco₃ * (2 mol hcl) / (1 mol caco₃) = 0.05 mol hcl * 2 = 0.1 mol hcl we have 0.1 mol hcl and concentration of hcl (0.002 mol/cm³).we need to find volumesince concentration = moles / volume, rearrange to get volume = moles / concentration volume = 0.1 mol / (0.002 mol/cm³) volume = 50 cm³

Another question on Chemistry

Chemistry, 22.06.2019 00:30

Which best describes why nh4+ can form an ionic bond with ci-?

Answers: 1

Answer

Chemistry, 22.06.2019 01:50

Ase your answer to this question on the information below.hydrocarbons and fissionable nuclei are among the sources used for the production of energy in the united states. a chemical reaction produces much less energy than a nuclear reaction per mole of reactant.the balanced chemical equation below represents the reaction of one molecule of a hydrocarbon with two molecules of oxygen.chemical equation: ch4 + 2o2 → co2 + 2h2o + 1.48 × 10−18 jthe nuclear equation below represents one of the many possible reactions for one fissionable nucleus. in this equation, x represents a missing product.nuclear equation: write an isotopic notation for the missing product represented by x in the nuclear equation.

Answers: 1

Answer

Chemistry, 22.06.2019 06:00

This flow chart shows the amount of energy that is emitted by each type of light. ultraviolet > blue light > yellow light > red light (maximum energy) (minimum energy) in an experiment, shining which type of light on a strip of metal would be least likely to produce the photoelectric effect? ultraviolet light dim blue light bright red light bright yellow light

Answers: 2

Answer

Chemistry, 22.06.2019 13:30

Which of the following has wavelength longer than the wavelength of viable light? a) x rays b) gamma rays c) radios waves d) ultraviolet waves

Answers: 1

Answer

You know the right answer?

Use the standard reaction enthalpies given below to determine ΔH°rxn for the following reactionP4(g)...

Questions