The combustion of acetylene in the presence of excess oxygen yields carbon dioxide and water: 2C2H2 (g) + 5O2 (g) → 4CO2 (g) + 2H2O (l) Calculate the value of ΔS° for this reaction in J/K· mol.

Astudent is given a sample of a blue copper sulfate hydrate. he weighs the sample in a dry covered porcelain crucible and got a mass of 23.875 g for the crucible, lid, and sample. the mass of the empty crucible and lid was found earlier to be 22.652 g. he then heats the crucible to expel the water of hydration, keeping the crucible at red heat for 10 minutes with the lid slightly ajar. on colling, he finds the mass of crucible, lid, and contents to be 23.403 g. the sample was changed in the process to very light clue anhydrous cuso4. if there are again 100.0 g of hydrate, how many grams of cuso4 are in it? how many moles of cuso4? (hint: molar mass of cuso4 = 159.6 g / mole. what per cent of the hydrate is cuso4? you may convert the mass of cuso4 to moles.)

Two nitro no2 groups are chemically bonded to a patch of surface. they can't move to another location on the surface, but they can rotate (see sketch at right). it turns out that the amount of rotational kinetic energy each no2 group can have is required to be a multiple of ε, where =ε×1.010−24 j. in other words, each no2 group could have ε of rotational kinetic energy, or 2ε, or 3ε, and so forth — but it cannot have just any old amount of rotational kinetic energy. suppose the total rotational kinetic energy in this system is initially known to be 32ε. then, some heat is removed from the system, and the total rotational kinetic energy falls to 18ε. calculate the change in entropy. round your answer to 3 significant digits, and be sure it has the correct unit symbol.

Imagine that you push on a large rock. at what point does your effort change the rock’s mechanical energy?