The principle quantum number of the first d shell is

The principal quantum number of the first d shell is three. The principal quantum number determines the size of the orbital. The secondary divides the shell into subshells called orbitals and designated by the letters s, p, d, f. From the sequence of the electron configuration, it can be seen that at a principal quantum number of three the d shell first appear.

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Dsolubility let me know if you have any other questions for chemistry