The zinc within a copper-plated penny will dissolve in hydrochloric acid if the copper coating is filed down in several spots (so that the hydrochloric acid can get to the zinc). the reaction between the acid and the zinc is as follows: 2h+(aq)+zn(s)→h2(g)+zn2+(aq). when the zinc in a certain penny dissolves, the total volume of gas collected over water at 25 ∘c was 0.949 l at a total pressure of 758 mmhg .

Mass of hydrogen gas evolved is 0.0749 grams.

Explanation:

Total pressure of the gases = p = 758 mmHg

Vapor pressure of water = 23.78 mmHg

Pressure of hydrogen gas ,P =  p - 23.78 mmHg = 758 mmHg - 23.78 mmHg

P = 734.22 mmHg =

Temperature  of of hydrogen gas ,T= 25°C =298.15 K

Volume of hydrogen gas = V = 0.949 L

Moles of hydrogen gas =n

PV = nRT (Ideal gas equation )

n = 0.03745 mol

Moles of hydrogen gas = 0.03745 mol

Mass of  0.03745 moles of hydrogen gas  = 0.03745 mol × 2 g/mol = 0.0749 g

Mass of hydrogen gas evolved is 0.0749 grams.

when 25.0 ml of 0.700 mol/l naoh was mixed in a calorimeter with 25.0 ml of 0.700 mol/l hcl, both initially at 20.0 °c, the temperature increased to 22.1 °c. the heat capacity of the calorimeter is 279 j/°c.

the equation for the reaction is:

naoh + hcl → nacl + h₂o

moles of hcl = 0.0250 l hcl ×

0.700

mol hcl

1 l hcl = 0.0175 mol hcl

volume of solution = (25.0 + 25.0) ml = 50.0 ml

mass of solution = 50.0 ml soln ×

1.00

ml soln

= 50.0 g soln

δt=t2-t1

= (22.1 – 20.0) °c = 2.1 °c

the heats involved are

heat from neutralization + heat to warm solution + heat to warm calorimeter = 0

q1+q2+q3=0

nδh+mcδt+cδt=0

0.0175 mol ×

δh

+ 50.0 g × 4.184 j·g⁻¹°c⁻¹ × 2.1 °c + 279 j°c⁻¹ × 2.1 °c = 0

0.0175 mol ×

δh

+ 439.32 j + 585.9 j = 0

0.0175 mol ×

δh

= -1025.22 j

δh=1025.22j0.0175 mol= -58 600 j/mol = -58.6 kj/mol

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