Chemistry, 20.11.2019 11:31 something69

21 .,plot a distance-time graph of the tip of the second hand of a clock by selecting 4 points on x-axis and y-axis respectively. the circumference of the circle traced by the second hand is 64 cm

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answer: the value of enthalpy change will be -152.80 kj.

solution:

pressure = 1atm , temperature = $25^oc$ = 298 k $)0^oc=273kelvins$

$o_3+3no\rightarrow 3no_2,\delta h_{reaction}=? [/)</p><p>[tex]\delta h_{no}=90.4kj/mol$

$\delta h_{no_2}=33.85kj/mol$

$\delta h_{o_3}=142.2kj/mol$

$\delta h_{reaction}=\sum \delta h_{products}-\sum\delta h_{reactants}=3\times\delta h_{no_2}-(3\times \delta h_{no}+\delta h_{o_3})$

$\delta h_{reaction}=33.85-(90.4+142.2)=-311.85kj/mol$

given that pressure and temperature are same in both gases , the number of moles of both gases can be determined by the ideal gas equation.

$v_{no}=12.00 l,v_{o_3}=8.50 l$

$pv_{no}=n_{no}rt=1atm \times 12.00 l=n_{no}\times 0.0821 atml/k mol \times 298 k$

$n_{no}=0.49 moles$

$pv_{o_3}=n_{o_3}rt=1atm \times 8.50 l=n_{o_3}\times 0.0821 atml/k mol \times 298 k$

$n_{o_3}=0.34 moles$

according to reaction 3 moles no are reacting with 1 mol of $o_3$ ,then 0.49 mol of no will react with $\frac{1}{3}\times 0.49$ moles of ozone that is 0.16 moles of ozone. since, no is limiting reagent and $o_3$ is an excessive reagent.

enthalpy change for the reaction between the given volumes of the gases is :

$\delta h_{reaction}\times \text{moles of no}=-311.85kj/mol\times 0.49 mol=-152.80kj/mol$

Answer from: Quest

Read the sentences below in 1962, i tried to enroll as the first black student at the university of mississippi. the governor of mississippi blocked my entrance which best describes the verbs used in the sentences? o they are past tense verbs, which are often used in narrative essays o they are past tense verbs, which are not often used in narrative essays. o they are future tense verbs, which are often used in narrative essays o they are future tense verbs, which are not often used in narrative essays.

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Answer from: Quest

Note that 2 mol dm⁻³ = 2 mol/(dm³)outline: we're given the concentration of hcl, which is 2 mol dm⁻³ (cubic meters in the denominator can represent volume, so i know this is concentration). we're an amount of calcium carbonate caco₃, which is 5 g. we're presented with a chemical equation which includes caco₃ and hcl. we are told to find the volume of hcl. from what we see so far, this seems to be a stoichiometry problem. we'll have to use the given information about calcium carbonate to find the amount of moles of hcl needed to fully react with calcium carbonate. then we'll have information about the moles of hcl and the concentration of hcl; that will be enough to figure out volume according to the formula concentration = moles / volume.======all the answer choices are not in dm.convert the given concentration so that it uses cm⁻³.we can use conversion factors. we have to cube our conversion factors so that dimensional analysis works.we can convert to meters first, using the fact that 10 dm = 1 m ⇔ 10³ dm³ = 1 m³then we use the fact that 10² cm = 1 m ⇔ (10² cm)³ = (1 m)³ ⇔ 10⁶ cm³ = 1 m³so converting: $\dfrac{\text{2 mol}}{\text{dm}^{3}} \cdot \dfrac{\text{10}^3\text{ dm}^3}{\text{1 m}^3} \cdot \dfrac{\text{1 m}^3}{10^6\text{ cm}^3} \\ \\ = \dfrac{\text{2 mol}}{1} \cdot \dfrac{\text{10}^3}{1} \cdot \dfrac{1}{10^6\text{ cm}^3} \qquad \text{\footnotesize cancelling units} \\ \\ = \dfrac{2\text{ mol}}{10^3 \text{ cm}^3} \\ \\ = 0.002\text{ mol/cm}^3$ now we have to find the moles of hydrochloric acid neededfind the moles of calcium carbonate. we have to find the molar mass of calcium carbonate, caco₃, which can be found by molar mass = (mass ca) + (mass c) + 3(mass o) = 40 + 12 + 3(16) = 100 g/molconvert the given 5 g to moles: mol caco₃ = 5 g caco₃ * 1 mol/(100 g) = 0.05 mol caco₃use stoichiometry (ratios) to figure out the moles of hcl needed. ratio wise, there's 2 hcls for every caco₃, so use dimensional analysis mol hcl = mol caco₃ * (2 mol hcl) / (1 mol caco₃) = 0.05 mol hcl * 2 = 0.1 mol hcl we have 0.1 mol hcl and concentration of hcl (0.002 mol/cm³).we need to find volumesince concentration = moles / volume, rearrange to get volume = moles / concentration volume = 0.1 mol / (0.002 mol/cm³) volume = 50 cm³

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21 .,plot a distance-time graph of the tip of the second hand of a clock by selecting 4 points on x-...

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