Boiling point and melting point of a gas?

Joe shines white light into a bowl half full of water at an angle of incident of 27.5°. calculate the angle of refraction in the water given the indices of refraction for air and water are 1.00 and 1.36, respectively.

How many grams of co(g) are there in 74.5 ml of the gas at 0.933 atm and 30o c?

Achemistry student weighs out 0.306 g of citric acid (h3c6h5o7), a triprotic acid, into a 250 ml volumetric flask and dilutes to the mark with distilled water. he plans to titrate the acid with 0.1000 m naoh solution. calculate the volume of naoh solution the student will need to add to reach the final equivalence point. be sure your answer has the correct number of significant digits.