The pressure of the saturated vapor of benzene (vapor in equilibrium with liquid) is 101.32 kpa at 80°c and 4.81 kpa at 5.5°c, respectively. the latter pressure and temperature correspond to the triple point of benzene. a) calculate the approximate molar heat of vaporization ahm of benzene (clausius - clapeyron equation). ahmv = 33.47 kj mol-1 b) what is the normal boiling point temperature of benzene? calculate the boiling point under a reduced pressure 10 kpa. b) 80°c and 20.4°c c) under what pressure benzene boils at 10°c? c) 6.05 kpa d) what is the saturated vapor pressure over solid benzene in the triple point (5.5°c)? d) 4.81 kpa

35. a insulated cylinder of solid gold (k 310 kw/m-k) of radius v2 m and height 5 m is heated at one end until the temperature at each point in the cylinder is given by w(r, y, z) (30 z2)(2-(r2+ y2). determine the rate of heat flow across each horizontal disk given by z 1, z 2, and z 3, identifying which has the greatest rate of heat flow across it.

explanation:

answer : the correct answer is 2) hno₃ and naoh .

arrhenius concept of acid and base :

acid :

according to arrhenius acid are those which release h⁺ or hydronium ion (h₃o⁺) in aqueous solution .

example : hcl +h₂o ↔ h₃o⁺ + cl⁻

hcl is giving h₃o⁺ ion in water , hence it is an arrhenius acid .

base :

according to arrhenius , bases are those which releases oh⁻ ions in aqueous solution .

example : koh (aq) ↔ k⁺ + oh⁻

since koh is producing oh⁻ ions hence , it is an arrhenius base .

checking the options :

1) ch₃oh and naoh :

ch₃oh is known as methanol , an organic compound , which is neutral compound . the dissociation of ch₃oh is negligible . it is very very weak acid (ka = 3.2 * 10 ⁻¹² ) .

naoh being ionic gives na⁺ and oh⁻ ions in aqueous solution as :

naoh ↔ na⁺ + oh⁻ . hence it is an arrhenius base

it can be concluded that ch₃oh and naoh is not arrhenius acid and base.

2) hno₃ and naoh :

hno₃ is an ionic compound which gives ions h⁺ and no₃⁻ ion in aqueous solution as:

hno₃ + h₂o ↔ h₃o⁺ + no₃⁻

since it is giving h⁺ ion . hno₃ is arrhenius acid .

naoh being ionic gives na⁺ and oh⁻ ions in aqueous solution as :

naoh ↔ na⁺ + oh⁻

. hence it is an arrhenius base .

it can be said that hno₃ and naoh are arrhenius acid and base.

3) ch₃oh and hcl

as discussed ch₃oh is neutral compound .

while hcl in aqueous solution dissociates to give h⁺ and cl⁻ ions as :

hcl + h₂o→ h₃o⁺ + cl⁻ . so hcl is arrhenius acid .

hence , ch₃oh and hcl are not arrhenius acid and base.

4) hno₃ and hcl :

hno₃ as discussed gives h⁺ in aqueous solution , while hcl also gives h⁺ in aqueous solution .

hence both hno₃ and hcl are arrhenius acid they are not acid and base .

so the arrhenius acid and base are 2) hno₃ and naoh.