Draw the correct mechanism for the first step of the reaction sequence. just show the reactants and curved arrows. do not show the products. include lone pairs and formal charges. only draw out acidic hydrogen with a covalent bond from the heteroatom from which the hydrogen are attached.

What can be added to the examples section of each circle? endothermic: ice melting into water, and a heat pack becoming warm exothermic: a glow stick glowing, and fireworks exploding endothermic: ice melting into water, and an instant ice pack turning cold exothermic: fireworks exploding, and gasoline burning endothermic: a glow stick glowing, and a heat pack becoming warm exothermic: an instant ice pack turning cold, and ice melting into water endothermic: gasoline burning, and an instant ice pack turning cold exothermic: ice melting into water, and an instant ice pack turning cold

A3.37-mg sample of protein was chemically digested to convert its nitrogen into ammonia and then diluted to 100.0 ml. then 10.0 ml of this solution was placed in a 50-ml volumetric flask and treated with 5 ml of phenol solution plus 2 ml of sodium hypochlorite solution. the sample was diluted to 50.0 ml, and the absorbance at 625 nm was measured in a 1.00-cm cuvette and found to be 0.486. for reference, a standard solution was prepared from 10.0 mg of nh4cl (molar mass = 53.49 grams/mole) dissolved in 1.00 l of water. then 10.0 ml of this standard was placed in a 50-ml volumetric flask, treated in the same manner as the unknown, and the absorbance found to be 0.323. finally, a reagent blank was prepared using distilled water in place of unknown, it was treated in the same manner as the unknown, and the absorbance found to be 0.076. calculate the weight percent of nitrogen in the protein.

13. a covalent bond between two atoms is likely to be polar if: a. one of the atoms is much more electronegative than the other. b. the two atoms are equally electronegative. c. the two atoms are of the same element. d. the bond is part of a tetrahedrally shaped molecule. e. one atom is an anion.