The volume and amount of gas are constant in a tire. the initial pressure and temperature are 1.82 atm and 293k. at what temperature will the gas in the tire have a pressure of 2.35 atm?

Although the diagram is not shown, i know that the convection is heated by a the core.

The problem here is that according to aufbau principle before 3d orbital 4s subshell comes.after filling 3p orbital with electrons you have 4 electrons left, you place two in 4s with opposite spin and the other two in 3d in any of its two orbitals of total five orbitals with the same spin.