Consider the solutions, 0.04 m urea [(nh2)2c=o)], 0.04 m agno3 and 0.04 m cacl2. which has (i) the highest osmotic pressure, (ii) the lowest vapor pressure, (iii) the highest boiling point?

i) Highest osmotic pressure: CaCl2

ii) lower vapor pressure : CaCl2

iii) highest boiling point : CaCl2

Explanation:

The colligative properties depend upon the number of solute particles in a solution.

The following four are the colligative properties:

a) osmotic pressure : more the concentration of the solute, more the osmotic pressure

b) vapor pressure: more the concentration of the solute, lesser the vapor pressure.

c) elevation in boiling point: more the concentration of the solute, more the boiling point.

d) depression in freezing point: more the concentration of the solute, lesser the freezing point.

the number of particle produced by urea = 1

the number of particle produced by AgNO3 = 2

the number of particle produced by CaCl2 = 3

As concentrations are same, CaCl2 will have more number of solute particles and urea will have least

i) Highest osmotic pressure: CaCl2

ii) lower vapor pressure : CaCl2

iii) highest boiling point : CaCl2

the reaction mixture contains some ammonia, plus a lot of unreacted nitrogen and hydrogen. the mixture is cooled and compressed, causing the ammonia gas to condense into a liquid. the liquefied ammonia is separated and removed. the unreacted nitrogen and hydrogen are then recycled back into the reactor .

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