On a summer day, you take a road trip through death valley, california, in an antique car you start out at a temperature of 21°c, but the temperature in death valley will reach a peak of 51°c. the tires on your car hold 15.6 l of nitrogen gas at a starting pressure of 249 kpa. the tires will burst when the internal pressure (pb) reaches 269 kpa. answer the following questions and show your work.